Rob Van Dam
RVD’s title win at ECW: One Night Stand in 2006 was a real feel good moment for the hardcore fanbase. Beating Cena in front of a red hot crowd in the ECW arena was definitely a career highlight for RVD, with years of hard work finally paying off on the big stage.
Unfortunately, Van Dam got busted for marijuana possession just three weeks after winning his belt, and as a result, the WWE had Edge beat him to take his belt on an episode of Monday Night Raw.
Van Dam was in the midst of a massive push when he got busted, and things could have worked out so much better for him had he just behaved himself.